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CSI: Dolomite

By Leonard Ho - Posted Dec 19, 2011 07:00 AM
One mystery has long baffled scientists: Why is dolomite (a calcium carbonate mineral like aragonite) so abundant in fossil coral reefs but seemingly absent in modern reefs? A serendipitous discovery may finally provide us the answer to this age-old head-scratcher, and the culprit is someone you know!
CSI: Dolomite

Coralline algae: The Ultimate Hideout? Hydrolithon onkodes at Scott Reef, Western Australia. © John Huisman

Reefkeepers are familiar with aragonite.  It's what we use for our sand, what our rocks are composed of, and what coral skeleton is formed with.  Aragonite is literally everywhere in modern coral reefs.

Reefbuilding corals make skeletons out of aragonite.
Reefbuilding corals make skeletons out of aragonite.
But in fossil reefs, this isn't the case;  Dolomite, not aragonite, dominates.  Like argaonite (and calcite), dolomite is a calcium carbonate mineral.  Dolomite's matrix is arranged differently than aragonite's, and dolomite is also loaded with magnesium.

Why is dolomite so prevalent in fossil reefs but seemingly absent in modern reefs?  Reefbuilding corals all form aragonite skeletons, not dolomite.  Did ocean chemistry shift through the millenia to favor aragonite formation over dolomite?  This phenomenon has long baffled scientists, but they may have accidentally stumbled upon the answer.

Scientists from the Research School of Earth Sciences, Australian National University found large quantities of dolomite packed inside a 'reef builder' species of encrusting coralline algae Hydrolithon onkodes while doing research on an unrelated subject.

Lead researcher Bradley Opdyke reports in the journal Biogeosciences:

"We have discovered that dolomite is in fact present in large quantities in modern coral reefs, but from an unexpected source.  The discovery was completely serendipitous - we were working on an unrelated question at the time.

When we confirmed the finding, I said to Marinda (Nash) [member of the research team], 'This is going to be huge. It opens up a kaleidoscope of future research topics'.

There was dolomite on the reefs all along, but it was hidden within these algae. This species... is found in abundance on reefs around the world.  The algae work with coral to 'cement' the reef structure to withstand the tremendous hydraulic pressure of waves."

So there you have it:  Dolomite on the lam ... now found.  We were just looking in the wrong place.  Coralline algae was harboring the fugitive all this time!

To learn more about calcite, aragonite, and dolomite, read James W. Fatherree, M.Sc.'s Advanced Aquarist article: Calcite, Aragonite, Limestone, and More.

[via Physorg.com]

Author: Leonard Ho
Location: Southern California

I'm a passionate aquarist of over 30 years, a coral reef lover, and the blog editor for Advanced Aquarist. While aquarium gadgets interest me, it's really livestock (especially fish), artistry of aquariums, and "method behind the madness" processes that captivate my attention.

Website: http://www.advancedaquarist.com.

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